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Constants
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1) Using the electrostatic potential to estimate the binding energy to the nearest hundredth of an eV of a positive and negative ion held in an ionic bond with a separation distance of
nm. Assume each has a charge of 1e.
2) What is the rotational energy to the nearest thousandth of an eV of a diatomic molecule with I= 1.5x10
-46
kg*m
2
in the L=
rotational state?
3) To the nearest micron what is the wavelength of the emitted photon if the molecule in the previous molecule makes a downward rotational transition?
4) A hypothetical diatomic molecule is composed of two identical atoms of mass 12 u, if the wavelength emitted when a L=2 to L=1 rotational transition occurs is
mm what is the rotational inertia? (Express your answer in scientific notation to 2 decimal places, i.e., 12345 would be 1.23e4)
5) What is the separation distance between the atoms in the previous question to the nearest pm?
6) A certain diatomic molecule has a vibrational frequency of 1.5x10
14
Hz and is in the 3rd vibrational state and the L=
rotational state (I=3.0x10
-46
kg*m
2
. If it makes a downward transition to the 2nd vibrational state, what is the maximum frequency (in units of 10
12
Hz to 2 decimal places) radiation that is emitted?
7) In the preceeding question what is the minimum frequency emitted (in units of 10
12
Hz to 2 decimal places)?
8) If a solar cell is be designed to absorb all of the Sun's radiation at wavelengths shorter than
nm , then what is the maximum electronic band gap energy of the p-n junction that will be used in the cell? Put your answer to the nearest meV (milli-eV) above 1.000 eV. (For example if your answer for the band gap is 1.151 eV you should enter 151 as your answer to the problem.)